Abstract
1. The approach considered can determine the equilibrium geometrical parameters of iminoxyl H2CNO. to within 0.02 A and 2° for the bond lengths and valence angles, respectively. 2. On forming the radical H2CNO. from the parent oxime the bond length r(N-O) decreases by 0.2 A, the angle CNO increases by about 15°, and the structural characteristics of the fragment H2C=N- remain practically unchanged.
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More From: Bulletin of the Academy of Sciences of the USSR Division of Chemical Science
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