Abstract
Cross-sections, photoelectron angular distribution parameters and branching ratios for the ionization of the outer-valence 5 a 1, 2 e and inner-valence 4 a 1 shells of phosphine have been calculated up to a photon energy of 90 eV. Ab-initio calculations have been performed, by the K-matrix technique and projection on basis sets of L 2 functions, in the random phase approximation for the three coupled ionization channels. The theoretical results, compared with the available experimental data and with recent semi-empirical calculations, show a quantitative agreement with the experiment.
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