Abstract
Based on the nitrogen-containing combustion, for the main reactions related to N2O in fuel combustion processes, the anharmonic and harmonic rate constant was calculated by using the method proposed by Yao and Lin according to the RRKM theory. For most reaction investigated in this study, the anharmonic effect was more obvious with increasing reaction temperature. Furthermore, with regard to some reactions, there was junction between the harmonic and anharmonic rate constant. Moreover, the study took advantage of the rate constant to fit the thermodynamic and kinetic parameters.
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