Abstract
AEOS, a previously proposed equation of state incorporating association in an explicit form is applied to calculate solid-liquid (SLE), liquid-liquid (LLE) and vapor-liquid equilibria (VLE) of strongly nonideal systems. The AEOS equation consists of two terms: a chemical one based on a continuous linear association model and a physical one represented by an equation of state for nonpolar fluids. The equation is able to reasonably predict the phase equilibria with the use of only pure component parameters. Only one adjustable binary parameter is sufficient for an accurate representation of mixture data. The obtained values of binary parameters are directly related to the acentric factor of inert components. The accuracy of simultaneous correlation of SLE, LLE and VLE is very satisfactory.
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