Abstract

The solubility of solid hydrocarbons and inorganics (carbon dioxide and hydrogen sulfide) in liquid hydrocarbons was correlated using the modified BWR equation of state of Lee and Kesler and the pseudocritical method to compute the fugacity coefficient of the solute in subcooled liquid. This method requires two binary parameters, k12 and s12, for each binary pair to be computed from experimental solid-liquid equilibrium data. These parameters are tabulated for a large number of binary systems. The correlation resulting from this investigation will be valuable in the design of cryogenic processes.

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