Abstract

The variational method is applied to the low-energy positron scattering and annihilation problem. The ultimate aim of the investigation is to find a computationally economical way of accounting for strong electron–positron correlations, including the effect of virtual positronium formation. The method is applied to the study of elastic s-wave positron scattering from a hydrogen atom. A generalized eigenvalue problem is set up and solved to obtain s-wave positron–hydrogen scattering phase shifts within 8×10−3 rad of accepted values. This is achieved using a small number of terms in the variational wavefunction; in particular, only nine terms that depend on the electron–positron distance are included. The annihilation parameter Zeff is also calculated and is found to be in good agreement with benchmark calculations.

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