Abstract

In this paper, we present new radiative rate calculations for forbidden transitions, namely magnetic dipole (M1) and electric quadrupole (E2) transitions, involving all the experimentally known energy levels within the 4f4 ground configuration of doubly ionized neodymium (Nd III). To do this, and in order to estimate the accuracy of the results obtained, two independent computational approaches based on the pseudo-relativistic Hartree–Fock and the fully relativistic Dirac-Hartree–Fock methods were used. The transition probabilities calculated with these two approaches showed good overall agreement, in particular for the most intense forbidden lines for which the relative differences did not exceed 25%. From these new atomic data, some astrophysical implications were deduced such as the possibility (or not) of observing some [Nd III] lines on the infrared spectra recorded by the James Webb Space Telescope, more precisely for the analysis of nebular phase kilonova spectra following compact object mergers.

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