Abstract

The perturbation formulae of EPR parameters g factors gx, gyand gzfor the lowest Kramers doublet of 4f1ion in orthorhombic symmetry are established. In these formulae, the contributions of the covalency effects, the admixture between J=7/2 and J=5/2 states as well as the second-order perturbation (which is not considered in the previous works) via crystal-field and orbital angular momentum interactions are all included. According to these formulae, and by using the superposition model, the g-factors gx, gyand gzfor Ce3+center in YBa2Cu3O6+ xsuperconductor are calculated. The results are discussed.

Full Text
Published version (Free)

Talk to us

Join us for a 30 min session where you can share your feedback and ask us any queries you have

Schedule a call