Abstract
The rate constants of the unimolecular dissociation of CF3XCF2CH3/D3(X = Cl, Br) and 1,2-ClF (1,2-BrF) interchanging to give CF3CF2XCH3/D3 (X = Cl, Br) molecules and 2,3-FH (FD) elimination, were calculated using the RRKM theory. For the unimolecular reactions of CF3BrCF2CH3/D3, the anharmonic effect for the non deuterated case was more obvious. It has been also found that the isotope effects are ∼2–5 times in this study. The anharmonic effect of the reactions chlorinated hydrocarbons Cl-CF3CF2CH3/D3 are greater than that of brominated hydrocarbons Br-CF3CF2CH3/D3. Furthermore, the kinetics parameters of reaction mechanism for those reactions were given.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
