Abstract
The enthalpies of the transfer of silver(I) ions from methanol to mixed methanol-acetonitrile solvents are calculated using the literature data. An estimative calculation of the enthalpies of transfer of the reaction of formation of [Ag18C6]+ upon a change in the solvent composition MeOH → AN is performed on the basis of previously found laws of change in the thermodynamic characteristics of complexation and solvation of reagents. It is shown that the governing factor in the change in the energy of the reaction is the enhancement of the solvation of the central ion.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
