Abstract
Calcium-β″-alumina and Nasicon were applied as solid electrolytes for SOx (x=2 or 3) gas detection. The following two galvanic cells with solid reference electrodes were assembled $$\begin{gathered} Pt|O_2 ,CaO||Ca - \beta '' - Al_2 O_3 ||CaSO_4 |SO_3 ,SO_2 ,O_2 |Pt \hfill \\ Pt|O_2 ,Na_2 O||Nasicon||Na_2 SO_4 |SO_3 ,SO_2 ,O_2 |Pt \hfill \\ \end{gathered} $$
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