Abstract
Starting from 1β-[(R)-2- hydroxy-1-methylethyl]-7aβ-methyl-3aα,6,7,7aβ-tetrahydroindane (1) syntheses have been effected of two bicyclic compounds suitable as intermediates for conversion into vitamin D-active products, viz. Windaus and Grundmann's ketone (20){7aβ-methyl-1β-[(1R,4R)-1,4,5-trimethylhex-trans-2-enyl]-3aα,4,5,6,7,7aβ-hexahydroindan-4-one}, and des-AB-cholestane-8β,25-diol (23){4β-hydroxy-1β-[(R)-5-hydroxy-1,5-dimethylhexyl]-7aβ-methyl-3aα,4,5,6,7,7aβ-hexahydroindane}.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callSimilar Papers
More From: Journal of the Chemical Society, Perkin Transactions 1
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
