Abstract
AbstractIn this work, a silicon‐, phosphorus‐, nitrogen‐containing flame retardant system was constructed via the combination of the caged organic octaphenyl silsesquioxane (OPS) and an intumescent flame retardant (IFR) composed of piperazine pyrophosphate and melamine polyphosphate. Compared with the IFR mixture alone, the designed OPS/IFR system simultaneously endowed polypropylene (PP) with a higher charring flame‐retardant effect and better mechanical properties under the same loading amount. With only 0.5 wt% OPS and 19.5 wt% IFR in PP, both 3.2 mm‐ and 1.6 mm‐thick flame‐retardant composite reached UL 94 V‐0 level, while the sample with IFR only passed the 3.2 mm‐thick UL 94 V‐0 rating. Moreover, compared with IFR, OPS/IFR with a specific mass ratio also performed higher limited oxygen indexes, improved anti‐dripping behavior in the glow‐wire test, and suppressed the heat and smoke release to a larger extent of PP composite. The main mechanism was that a phosphorus/silicon synergistic charring effect occurred in PP composites during the combustion, thus forming more compact char layers with rich phosphorus/silicon compounds. The investigation of the multielement OPS/IFR system also disclosed a more effective flame retardant working way in PP through synergistic charring effect. Meanwhile, due to the mico‐nanoscale dispersibility of OPS in PP, the constructed composites kept higher mechanical performances compared with the sample loaded with IFR alone.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.