Abstract
Modified galvanic cell arrangements using CaF2 solid electrolytes have been used to measure the sulphur potential of Mn-MnS and of Fe-FeS.The galvanic cell used were:(This article is not displayable. Please see full text pdf.) The data can be represented as a linear function of temperature:(This article is not displayable. Please see full text pdf.) The standard molar free energies of formation of MnS and FeS were calculated using the data of the standard molar free energy of formation of Ag2S reported by Thompson and Flengas:(This article is not displayable. Please see full text pdf.) \ oindentThe results were compared with reported values.
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