Abstract

The crystal structures of [ meso-tetra-( p-chlorophenyl)porphyrinato](pyridine)cadmium(II) pyridine solvate Cd[( p-Cl) 4tpp](py) · py [or 5 · py], and [ meso-tetra-( p-chlorophenyl)porphyrinato](dimethylformamide)cadmium(II) toluene solvate Cd[( p-Cl) 4tpp](DMF) · toluene [or 6 · toluene] were determined. The ring current effect provides a complementary method for the investigation of coordinated pyridine and DMF ligand in complexes 5 and 6, respectively.

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