Abstract
The multi-cationic site occupation control of rare earth doped phosphor materials is one of the key factors in achieving single-phase full-spectrum emission. In this work, the site distribution of Eu2+ in Ca9NaGd0.667(PO4)7 (CNGP):x%Eu2+ phosphors with multi-cationic sites was determined. Under 385 nm excitation, CNGP:x%Eu2+ samples exhibited a cyan emission composed of three sub-Gaussian components. The CNGP:1.5%Eu2+ phosphor was structurally modified through the partial substitution of Mg2+ for Ca2+ according to the crystallographic site engineering theory, and corresponding luminescent properties had been adjusted. When the concentration of Mg2+ changed, the Ca9-yMgyNaGd0.667(PO4)7:1.5%Eu2+ (CNGPE:yMg2+) phosphors exhibited a tunable emission from cyan to orange and achieved white light emission at y = 0.6. Based on the change of the crystal field environment, the mechanism of Mg2+ substitution affecting the luminescence characteristics of CNGP:x%Eu2+ phosphors was researched in detail. The light-emitting diode device consisted of a CNGPE:0.6Mg2+ phosphor and a 385 nm chip and had a high color rendering index (CRI = 91.9), low correlated color temperature (CCT = 4852 K), and excellent color stability. The optical performance of this device makes it promising to be used in full spectrum lighting.
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