(Ca,Mg)9Gd1 –xEux(PO4)7 Red Phosphors Activated with Gd3+ and Eu3+

Abstract

Solid solutions with the whitlockite structure Ca9Gd1 –хEux(PO4)7 and Ca8MgGd1 –хEux(PO4)7 were synthesized by standart tecnique. The compounds have been characterized using various methods, including X-ray diffraction, second harmonic generation, and luminescence spectroscopy. The optical characteristics, excited-state lifetimes, and quantum yield were studieid. Under excitation at 395 nm, the compounds exhibit bright luminescence in the orange-red spectral region. The concentration of Eu3+ cation were optimized for obtaining the most efficient luminescence in the red spectral region: x = 0.75 for Ca8MgGd1 –хEux(PO4)7 and x = 1 for Ca9Gd1 –хEux(PO4)7. Efficient Gd3+ → Eu3+ energy transfer has been demonstrated, with an increase in photoluminescence intensity by a factor of 2.5. The quantum yield in the solid solutions reaches 49.5%, which is twice that in a commercially available Y2O3:Eu3+-based phosphor.