Abstract
Experimental data are presented on the electrical conductivity, ionic transference numbers, and phase transitions of Ca3 – x La2x/3(VO4)2 (0 ≤ x ≤ 1) vanadates, which are shown to be Ca ionic conductors. The highest Ca ion conductivity is found in Ca2La2/3(VO4)2 (palmierite structure) at low temperatures and in β"-Ca3(VO4)2 (whitlockite-like structure) at high temperatures. The mechanisms of Ca2+ transport are discussed.
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