Abstract
Hydrothermal reaction of Zn(OAc)2⋅2 H2O and H3PO3 in the presence of n-butylamine gives the title compound, which contains extra-large 24-ring channels (see framework representation). Each channel is enclosed by a tetragonal array of four 8-ring channels interconnected by corner-sharing 4-ring chains through Zn-O-P linkages.
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