Abstract
An efficient Selectfluor-oxidative protocol was developed for the direct C2-arylacylation of 2H-benzothiazoles via the radical reaction of 2H-benzothiazoles with methyl arenes. Selectfluor can effectively promote the oxidative cross-coupling without an external catalyst. This arylacylation reaction tolerates a wide range of functional groups affording 28 examples of the arylacylated products in 39–81% yield.
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