Abstract
Thermolysis of the dithiocarbamate complex 1 led to the formation of the thiocarbenoid complex 2 and two double cubanes: 3, which has an intercubane Cr-Cr bond and a dithiooxamide ligand in the μ-η2 ,η4 bonding mode, and 4, which contains two dithiocarbamate ligands in the μ-η1 ,η2 bonding mode.
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