Abstract
A set of organoantimony(III/V) and organobismuth(V) fluorides (i.e. LSbF2, LSbClF, LPh2SbF2, LSbF4 and LPh2BiF2) bearing the 2-{[(2,6-diisopropylphenyl)imino]methyl}phenyl- as a C,N-chelating ligand (L) has been prepared using LCNR2SnF (where LCN = 2-(N,N-dimethylaminomethyl)phenyl); R = n-Bu or Ph) and/or XeF2 as fluorinating agents. All species were characterised by the combination of elemental analysis and multinuclear solution NMR spectroscopy. Solid-state structures of all complexes were established by the sc-XRD analysis. In addition, theoretical calculations were carried out to corroborate the experimental results. Preparation and structural characterisation of LSbI2 is also reported.
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