Abstract

AbstractPolyaniline nanofiber as a macroligand for the supportedcuprous iodide catalyst (CuI‐PANInf) has been developed for the coupling of aryl halides (including aryl chlorides) with aliphatic, aromatic, and N(H)‐heterocyclic amines under ambient conditions (80 °C for aryl chlorides) has been developed. This simple and efficient method for coupling reactions is highly versatile, convenient, and also the catalyst can be used for several cycles with good‐to‐excellent yields.

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