Abstract
The photodissociation of 1-bromo-3-chloropropane was studied at 234 and 265nm using ion velocity imaging technique. Bromine fragments in this study were produced via direct dissociation of C–Br bond. The speed and angular distributions of Br∗ and Br were measured. The appearance of chlorine fragments at 234nm was assigned to a secondary dissociation process. The contributions of three excited states: 1Q1, 3Q0 and 3Q1 were estimated at each wavelength. Comparing with previous results, the study reveals more details about the dynamics of molecules with multichromophores.
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