Abstract

Dichlorocarbene generated by pyrolysis of sodium trichloroacetate was found to add to C 60 in a benzene-diglyme mixed solvent. The products C 60CCl 2) n (n=1-3) were isolated by means of gel permeation chromatography eluted with toluene and characterized by FAB mass spectroscopy. The structure Of C 60(CCl 2) was determined by 13C NMR spectroscopy. The addition occurred at the 6-ring/6-ring junction, giving a cyclopropane structure.

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