Abstract
The electronic state of carbon in trigonal prismatic environment in [Re 12CS 17(CN) 6] n − complexes with variable redox state n = 6 ↔ 8 was studied by molecular orbital method and electron localization function. The state is characterized by sp 2-hybridisation and oxidation state −4. A weak long-distance interaction between μ 6-С and μ 2-S in the group [(μ 6-С)(μ 2-S) 3] was discovered for n = 6, the interaction disappears for n = 8.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
