Abstract
The crystal structure of (C4H14N2)2[H2V10O28] symmetry lying on a centre of symmetry, and two butane-1,4-diammonium cations per anion for charge compensation. The anion is protonated on centrosymmetrically related μ-OV3 groups; this is a less common protonation mode for dihydrogendecavanadates. Anions are involved in a two-dimensional hydrogen-bonding network, forming a layered structure.
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