Abstract

The thermal expansion and contraction property of phase change materials (PCMs) is a significant factor in affecting the buoyancy-driven melting/solidification heat transfer performance in latent heat storage (LHS) units. To reveal the intrinsic mechanisms, a mathematical model of buoyancy-driven melting/solidification processes in finned LHS units is constructed. The phase-change behaviors, thermal transport properties of different PCMs, and roles of heat transfer fluid (HTF) direction and fin layout in melting/solidification performance are explored. The results indicated that when compared to conduction-dominated cases, the buoyancy-driven melting duration of gallium and n-octadecane increases by 1.8% and decreases by 32.6%, respectively, while the corresponding solidification times decrease by 8.4% and increase by 15.2%, respectively. The downward HTF enhances the melting rate of gallium with thermal-contraction properties and the solidification rate of n-octadecane with thermal-expansion properties. Conversely, the upward HTF enhances the melting rate of n-octadecane with thermal-expansion properties and the solidification rate of gallium with thermal-contraction properties. For finned LHS units with upward HTF, the ladder-type and reverse ladder-type fins facilitate the melting performance of n-octadecane and gallium, respectively. Moreover, the ladder fins with non-uniform layouts weaken the solidification performance of PCMs with different thermal characteristics.

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