Abstract
1,1′‐Ferrocenyl ligands featuring either bulky dioxaphosphepine (L1) or diazaphospholene (L2) donor moieties have been prepared, crystallographically characterized, and tested in representative nickel‐catalyzed C–N cross‐coupling reactions. Ligand L1 proved competent in cross‐couplings involving primary/secondary alkylamine or indole nucleophiles with (hetero)aryl chlorides, with the catalytic performance of rac and meso‐L1 differing in the case of some substrate pairings. Conversely, L2 proved ineffective under analogous conditions.
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