Bulk propylene polymerization in the presence of ansa-metallocenes of C 2 and C 1 symmetries: From a rigid thermoplastic to elastomeric stereoblock polypropylene

Abstract

Bulk propylene polymerization in the presence of ansa-metallocenes with C2 and C1 symmetries has been studied. The catalytic activity, polymerization kinetics, and the molecular weight of polypropylene (PP) depend strongly on catalyst formation conditions. Mixtures of rac and meso isomers of metallocenes make it possible to rapidly produce a high-molecular-weight isotactic PP with high stereoregularity and mechanical characteristics and thus skip the stage of the isolation of pure rac isomer in the catalyst synthesis. The ability of triisobutylaluminum to serve as a cocatalyst is studied for ansa-metallocenes of C1 symmetry. In this case, the molecular weight of PP is higher, indicating that organoaluminum compounds participate in chain termination reactions. An increase in the reaction temperature results in an increase in the stereoregularity and crystallinity of PP. Polypropylene synthesized using ansa-metallocenes of C1 symmetry has good elastomeric properties.