Abstract
This paper studies the phenomenon of spontaneous boiling-up of polymeric liquids on heating at rates \((\dot T)\) up to 107 K·s−1. A model of the thermal equation of state for (polymer + monomer) systems and a procedure for determination of the spontaneous boiling-up temperature T* for polymeric liquids, taking decomposition into account, are proposed. The experimental data on T*\((\dot T)\) for a number of polymer melts are compared with results calculated from the model.
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