Abstract
Im ersten Schritt einer hoch regioselektiven Synthese von cyclischen Sulfamiden mit Bicyclo[3.3.0]octan-Gerüst (siehe Schema) greift das innere Sulfamid-Stickstoffatom nucleophil am zentralen Kohlenstoffatom der Alleneinheit an. Eine zweite, gleichfalls intramolekulare nucleophile Addition des äußeren Sulfamid-Stickstoffatoms führt zum bicyclischen Produkt.
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