Abstract

The authors compare symmetry-breaking in thermodynamic equilibrium systems (leading to phase change) and in systems far from equilibrium (leading to dissipative structures). They conclude that the only similarity between the two is their ability to lead to the emergent property of spatial variation from a homogeneous background. There is a well-developed theory for the equilibrium case involving the order parameter concept, which leads to a strong correlation of the order parameter over macroscopic distances in the broken symmetry phase (as exists, for example, in a ferromagnetic domain). This correlation endows the structure with a self-scaled stability, rigidity, autonomy, or permanence. In contrast, the authors assert that there is no developed theory of dissipative structures (despite claims to the contrary) and that perhaps there are no stable dissipative structures at all! Symmetry-breaking effects such as vortices and convection cells in fluids—effects that result from dynamic instability bifurcations—are considered to be unstable and transitory, rather than stable dissipative structures.

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