Abstract
Calcite crystals were grown from solution with single-crystal dimensions up to 3 mm and doped up to ∼0.1 at% with Nd3+ ions. Phase purity was verified by powder X-ray diffraction. The concentration of Nd3+ was measured by energy-dispersive spectrometry and Rutherford backscattering spectrometry. Micro X-ray fluorescence mapping of the calcite grains indicates uniform Nd distribution in as-grown crystal grains. X-ray absorption fine structure suggests that Nd3+ is substituted for Ca2+ with local lattice distortion. Temperature-dependent near-infrared spectroscopy of Nd3+ impurities in calcite reveals large inhomogeneous linewidths and smooth line profiles that are characteristic of glassy hosts, though the samples are well crystallized.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.