Brine leaching of lead-bearing zinc plant residues: Process optimization using orthogonal array design methodology

Abstract

Orthogonal array design (OAD) has been used to arrange the experimental runs in order to maximize lead recovery and also minimize zinc dissolution from an Iranian zinc plant residue (ZPR). The residue assaying 9.21% Zn, 12.37% Pb and 5.31% Fe was used in successive processes involving sulfuric acid (H 2SO 4)–water leaching to bring zinc into solution and therefore enrich the lead in the residue and then brine leaching for lead recovery. An L 25 orthogonal array (OA, five factors in five levels) was employed to evaluate the effects of NaCl concentration ( C brine = 50, 150, 200, 250, 300 g/L), time ( t = 10, 20, 30, 40 and 50 min), pulp density ( S / L = 25, 50, 100, 150 and 200 g/L), pH (1, 2, 3, 4, 5) and stirring speed ( R = 100, 200, 300, 400 and 500 rpm) on extraction of the individual metal ions (Pb, Zn, Fe). Statistical analysis, ANOVA, was also employed to determine the relationship between experimental conditions and yield levels. The results showed that increasing pulp density and initial pH reduced mean responses for lead. However, increasing brine concentration promoted the recovery of lead. The experimental results for selective leaching showed that under optimal leaching conditions ( S / L) 1: 25 g/L, (pH) 1:1, t 3:30 min, ( C brine) 5: 300 g/L and R 4: 400 rpm, the extraction of lead and zinc were 89.43% and 3.84%, respectively; giving a solution containing 2.99 g/L Pb, 0.02 g/L Zn and negligible amount of iron.