Abstract

Color centers in silicon carbide have recently emerged as one of the most promising emitters for bright single-photon emitting diodes (SPEDs). It has been shown that, at room temperature, they can emit more than 109 photons per second under electrical excitation. However, the spectral emission properties of color centers in SiC at room temperature are far from ideal. The spectral properties could be significantly improved by decreasing the operating temperature. However, the densities of free charge carriers in SiC rapidly decrease as temperature decreases, which reduces the efficiency of electrical excitation of color centers by many orders of magnitude. Here, we study for the first time the temperature characteristics of SPEDs based on color centers in 4H-SiC. Using a rigorous numerical approach, we demonstrate that although the single-photon electroluminescence rate does rapidly decrease as temperature decreases, it is possible to increase the SPED brightness to 107 photons/s at 100 K using the recently predicted effect of hole superinjection in homojunction p-i-n diodes. This gives the possibility to achieve high brightness and good spectral properties at the same time, which paves the way toward novel quantum photonics applications of electrically driven color centers in silicon carbide.

Highlights

  • Color centers in diamond and related wide-bandgap semiconductors are considered one of the most promising emitters for practical single-photon sources (SPSs), which are vital for many quantum information technologies, ranging from unconditionally secure quantum communication lines to optical quantum computers [1,2,3]

  • The contact resistance can significantly affect the current–voltage characteristic, especially at low temperatures, it has been demonstrated that the dependence of single-photon electroluminescence (SPEL) rate on the current in diamond single-photon emitting diodes (SPEDs) is very robust to the contact resistance variation [30]

  • The contact resistance can significantly affect the current–voltage characteristic, especially at low temperatures, it has been demon4 of 9 strated that the dependence of SPEL rate on the current in diamond SPEDs is very robust to the contact resistance variation [30]

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Summary

Introduction

Color centers in diamond and related wide-bandgap semiconductors are considered one of the most promising emitters for practical single-photon sources (SPSs), which are vital for many quantum information technologies, ranging from unconditionally secure quantum communication lines to optical quantum computers [1,2,3]. It recently became apparent that the physical properties of diamond limit the range of its possible practical applications. 5.5 eV, diamond features the activation energy of donors of as high as 0.6 eV [5], which seriously limits the maximum density of free electrons. Silicon carbide can host optically active point defects, Nanomaterials 2021, 11, 3177.

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