Bright and Switchable Whiteness in Macro‐Crosslinked Hydrogels

Abstract

AbstractBright white color is often achieved in nature by the combination of polydisperse scattering structures and high refractive index contrast between the scatterer and the surrounding medium. Similarly, synthetic systems have commonly utilized inorganic materials as the scattering centers to achieve white color, which, however, lacks the ability to switch the optical properties. While hydrogels capable of scattering light are utilized in applications such as smart windows, their reflection properties have remained limited due to the low refractive index contrast between the polymer and water. As a result, thick layers in the millimeter range are often required to achieve reasonable whiteness. Here a hydrogel consisting of a temperature‐responsive poly(N‐isopropylacrylamide) (PNIPAm) and chemically modified agarose used as a chemical macro‐crosslinker is presented. The hydrogel exhibits high whiteness at temperatures above the phase transition (≈31 °C). The reflectance at 800 nm is four times as high as for standard PNIPAm, and a change in transmittance can be induced by laser pulses as short as 30 ms. The macro‐crosslinked structure of this hydrogel provides superior reflectance at a lower thickness compared to reported hydrogel systems, enabling a variety of potential applications including smart windows, responsive displays, optical switches, and camouflage.