Bridging Au nanoclusters with ultrathin LDH nanosheets via ligands for enhanced charge transfer in photocatalytic CO2 reduction

Abstract

Au nanoclusters (NCs) bring new opportunities for constructing visible-light photocatalysts for solar-driven CO2 conversion, whereas the agglomeration under illumination and lack of catalytic sites severely hinder their application. One promising approach to address the limitations is the confinement of Au NCs on a heterogeneous substrate with efficient catalytic sites, in which a concomitant bottleneck originates from the electron transfer between Au NCs and catalytic sites determining the charge transfer dynamics. Herein, we develop an effective strategy for grafting Au NCs onto ultrathin layered double hydroxide (LDH) nanosheets via engineering bridging ligands. The bridging ligands function as both surface anchors and electron mediators, which confine and stabilize Au NCs on LDH, as well as facilitate electron transfer from Au NCs to catalytic sites. As a result, the durability and efficiency for photocatalytic CO2 reduction is significantly enhanced. This work provides a fresh hint for stabilizing ultrasmall nanoclusters and facilitating the electron transfer between light-harvesting nanoclusters and catalytic sites through bridging ligands.