Bridged Polysilsesquioxanes with Improved Second Order Nonlinear Optical Properties and Stability

Abstract

ABSTRACTWe report the synthesis and sol-gel polymerization of 4-nitro-N,N-bis[(3- triethoxysilyl)propyl]aniline 1. An efficient synthesis of the monomer was developed by the hydrosilylation of N, N-diallyl-4-nitroaniline. Optical quality thin films were synthesized by spin coating an n-butanol solution of 1 using formic acid as catalyst and source of water. We improved the temporal stability of the NLO signal from films prepared from 4-nitro-N,N-bis[(3-triethoxysilyl)propyl]aniline by increasing the intensity of the poling field and extending the heating period during the poling/curing stage. By Maker fringe analysis, a X(2) value of 9 × 10−8 esu was measured for these polysilsesquioxanes. If one assumes that the major component of the NLO effect is along the z-axis, the X(2) value corresponds to a d33 coefficient of 18.9 pm/V and a r33 value of 4.7 pm/V.