Brick kiln exhaust as a source of polycyclic aromatic hydrocarbons (PAHs) in the surrounding soil and plants: a case study from the city of Peshawar, Pakistan

Abstract

The purpose of the present study was to investigate the effects of brick kiln exhaust on the quantity of polycyclic aromatic hydrocarbons in surrounding soils and plants. In Pakistan, a big problem is the rapid conglomeration of the brick kilns in out skirt of nearly all urban centers to cope with the rapid construction work in big cities. A huge amount of low-grade coal, rubber, tires is used in non-scientific manner. The study was conducted in the City of Peshawar the capital of Kyber Pakhtunkhwa where many brick kilns are located in the periurban areas. Soil and medicinal plants samples were collected from different locations around the bricks kiln and were analyzed for selected polycyclic aromatic hydrocarbons (PAHs), i.e., benzo(a)pyrene, anthracene, chrysene, flourene, flouranthene, phenanthrene, naphthalene, and acenapthylene. Quantitative and qualitative analysis was carried out by UV spectrophotometer and high-performance liquid chromatography. Benzo[a]pyren and Chrysene were found to be the most abundant compounds. The total load of PAHs in the central location was found to be 0.4014 mg/kg. General trend of PAHs distribution was such that the concentration of individual PAHs was found to increase with depth clearly indicating their absorption in the soil. PAHs concentration increased with the distance up to 300 m and then gradual decreased which showed their movement with the water and air. The PAHs load was found high in the leaves as compared to stem and roots. This high load in the aerial parts indicated their excretion route as well as air deposition.