Abstract
BackgroundThe energy requirements are globally on a rapid escalation, as technology advances, which is also true for a developing country like Nigeria, which is dependent on fossil fuels and its derivatives. Apart from its adverse effect on its economy, it has also negative impacts on the health and the environment, in general. However, investments in renewable energy are faced by the competitive oil prices, the very high investment cost for renewable energy, and high local electricity prices. This paper appraises the attractiveness of investing in renewable energy sources over the continued use of non-edible oil for electricity generation.MethodsThis paper explores the application of biomass seed oil to produce a renewable fuel (biodiesel) using heterogeneous base catalyst. Meanwhile, two-step processes were employed to produce the biofuel. In the first step (esterification), the acid value of the oil was reduced to the recommended limit (FFA ≤ 1.5) using H2SO4, while in the second step (transesterification), the catalyst calcination of grounded Brette Pearl Spar Mable (BPSM) pre-soaked in methanol was used as a biobase for biodiesel production. For the optimization, minitab response surface (MRS) and artificial neural network (ANN) were employed to model and optimize the process variables responsible for the optimum production of the oil and the biodiesel.ResultsThe result presented showed that T. peruviana seed was found to be rich in oil with an average yield of 44.00% (w/w), and the oil was highly unsaturated with a high FFA. The maximum experimental biodiesel yield obtained was 86.00% at a catalyst amount of 4 g, a reaction time of 70 min, and a methanol/oil ratio of 0.1(v/v). This result was validated in triplicate under the same conditions, which yielded 85.70% (v/v) for MRS and 85.98% (v/v) for ANN. Furthermore, the optimization results also indicated that the p values (p < 0.05) of the model terms were significant, and the accuracy of the models achieved by MRS and ANN based on R2 depict that both optimization tools gave good predictions of R2 (MRS: R2 = 99.98% and ANN: R2 = 99.97%). The properties of the biodiesel, as described in other earlier reports using the same feedstock with different catalysts, indicated that the produced biodiesel had properties which agreed to those reported in the literature.ConclusionsT. peruviana seed has proved to be a good biomass raw material for oil production, and its conversion to biofuel using a heterogeneous biobase catalyst showed its suitability as a renewable environmental friendly fuel. Government should invest in more sustainable sources of energy by imposing law for the use of non-edible oil or decreasing the price of electricity.
Highlights
The energy requirements are globally on a rapid escalation, as technology advances, which is true for a developing country like Nigeria, which is dependent on fossil fuels and its derivatives
T. peruviana seed has proved to be a good biomass raw material for oil production, and its conversion to biofuel using a heterogeneous biobase catalyst showed its suitability as a renewable environmental friendly fuel
The observation from this study, which implies that K is the major active component responsible for the activity of the catalyst in Brette Pearl Spar Mable (BPSM) synthesis can be supported by the findings reported by Betiku et al [35], where K with 59.3% has the highest concentration among other elements such as calcium, magnesium, phosphorous, and others present in calcinated cocoa pod husk used in biodiesel production from Azadirachta indica seed oil
Summary
The energy requirements are globally on a rapid escalation, as technology advances, which is true for a developing country like Nigeria, which is dependent on fossil fuels and its derivatives. Oils were usually extracted from oil seeds through various methods such as mechanical [6,7,8], pressurized solvent extraction [9], soxhlet extraction [10], ultrasonic extraction [11, 12], aqueous enzymatic oil extraction (AEOE) [13, 14], stirring and shaking extraction [15] to mention a few These methods have been reported to be used for the extraction of vegetable oils and other plant essential components, each with intrinsic advantages and shortcomings [16]. Betiku et al [24] investigated the solvent extraction of oil from Beniseed (Sesamum indicum) oilseeds. These oils have already been applied as feedstocks in many applications, such as paint, pharmaceuticals, cosmetics, and others
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