Abstract

After the Deepwater Horizon oil platform explosion, an estimated 172.2 million gallons of gas-saturated oil was discharged uncontrollably into the Gulf of Mexico, causing the largest deep-sea blowout in history. In an attempt to keep the oil submerged, massive quantities of the chemical dispersant Corexit® 9500 were deployed 1522m deep at the gushing riser pipe of the Macondo prospect’s wellhead. Understanding the effectiveness of this unprecedented Sub-Sea Dispersant Injection (SSDI) is critical because deep-water drilling is increasing worldwide. Here we use the comprehensive BP Gulf Science Data (GSD) to quantify petroleum dynamics throughout the 87-day long blowout. The spatio-temporal distribution of petroleum hydrocarbons revealed consistent higher concentrations at the sea surface and in a deep intrusion below 1000 m. The relative importance of these two layers depended on the hydrocarbon mass fractions as expected from their partitioning along temperature and pressure changes. Further, analyses of water column Polycyclic Aromatic Hydrocarbons (PAH) of GSD extensively sampled within a 10-km radius of the blowout source demonstrated that substantial amounts of oil continued to surface near the response site, with no significant effect of SSDI volume on PAH vertical distribution and concentration. The turbulent energy associated with the spewing of gas-saturated oil at the deep-sea blowout may have minimized the effectiveness of the SSDI response approach. Given the potential for toxic chemical dispersants to cause environmental damage by increasing oil bioavailability and toxicity while suppressing its biodegradation, unrestricted SSDI application in response to deep-sea blowout is highly questionable. More efforts are required to inform response plans in future oil spills.

Highlights

  • On April 20th, 2010, the Deepwater Horizon (DWH) blowout – one of the largest oil spill disasters in history – took place in the Gulf of Mexico at a depth of 1,522 m

  • The dynamic physiochemical processes that transport petroleum hydrocarbons in the water column depend on the gas-to-oil ratio, the type and behavior of “live oil” under variable hydrostatic pressure, and on turbulent flows and ambient currents near the wellhead (Tolman, 1949; Aman et al, 2015)

  • Despite irregular sampling employed during collection of the BP Gulf Science Data (GSD), a clear signal emerges through time (Figure 2)

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Summary

Introduction

On April 20th, 2010, the Deepwater Horizon (DWH) blowout – one of the largest oil spill disasters in history – took place in the Gulf of Mexico at a depth of 1,522 m. With a flow rate in the range of 50,000–70,000 bbl/d (Griffiths, 2012) and stratificationdominated currents, a live oil plume became trapped at levels of neutral buoyancy (Aman et al, 2015), leading to formation of intrusion layers (Camilli et al, 2010; Kessler et al, 2011). The dissolution and biodegradation of the live oil as it rose in the water column lead to hydrocarbon partitioning between organic and aqueous phases. These key processes dictate the spatio-temporal dynamics of the oil spilled (Ryerson et al, 2011; Camilli et al, 2012). A detailed temporal analysis of the distribution of hydrocarbons in the water column is still lacking

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