Abstract
Nanocrystalline diamond (NCD) films are being used in a large number of applications. Also, diamond nanorods (DNRs) exhibit distinctive features that are not present in diamond films, because of the tunable large surface-to-volume ratio and tubular configuration. In this work, we report on the synthesis of DNRs by means of the bottom-up and template-free method from NCD films by the hot filament chemical vapor deposition system. The substrate materials used for diamond deposition were stainless steel (AISI 316) and chromium nitride-coated stainless steel. On both substrates, NCD films and then DNRs have been synthesized. The micro-Raman confirms that the synthesized structure is NCD. In addition, the grazing incident x-ray diffraction pattern confirms the presence of cubic diamond and rhombohedral diamond as a film on the CrN and Cr2N interlayer. Also, the DNRs are encased in an amorphous carbon (a-C) shell. The DNRs are grown on the NCD grains by a bottom-up technology and template-free method. Their orientations are almost random in the diamond thin-film surface. In addition, the density of DNRs on the NCD film for the CrN interlayer is more than for the stainless-steel substrate. The NCD/DNR films are dense, adhesive, continuous, and almost uniform on the CrN-coated stainless-steel substrate.
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