Abstract
Borylated β-fluorinated pyrroles, which are molecules with the potential to be converted into π-extended derivatives, were synthesized using IrI-catalyzed reactions and their solid-state assembled structures via hydrogen bonding between the pyrrole NH and Bpin-O were revealed. The deprotonated species detected by ESI-TOF-MS suggest the formation of anionic species, which are promising building blocks for ion-pairing assemblies. Borylated β-fluorinated pyrroles, which are molecules with the potential to be converted into π-extended derivatives, were synthesized using IrI-catalyzed reactions and their solid-state assembled structures via hydrogen bonding between the pyrrole NH and Bpin-O were revealed. The deprotonated species detected by ESI-TOF-MS suggest the formation of anionic species, which are promising building blocks for ion-pairing assemblies.
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