Abstract

Two-dimensional (2D) boron nitride (BN) nanosheets, the rising material stars, have unique properties and amazing functionalities. The concise history of diverse synthesis routes of BN nanosheets is briefly summarized here; and the recent development towards mass production of BN nanosheets, i.e. "chemical blowing" technique relying on blowing molten polymer precursors into large polymeric bubbles and subsequent annealing into BN bubbles/nanosheets, is focused on. The abundant BN nanosheets enable their applications, especially in the representative polymeric composites with BN nanosheet additives, as particularly highlighted in this review. The highly thermoconductive insulating BN-filled composites are thus envisaged as high-performance packaging materials for electrical circuits.

Highlights

  • boron nitride (BN) nanosheets are (002) mono-/few-layered hexagonal BN (h-BN)

  • We developed a new strategy, so-called “chemical blowing” [32,33], which relies on making large bubbles with atomically thin B-N-H polymer walls starting from ammonia borane (AB) compound as a precursor (Figure 4)

  • BN nanosheets are the representatives of 2D crystals having unique properties

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Summary

Related content

- High-yield boron nitride nanosheets from ‘chemical blowing’: towards practical applications in polymer composites Xuebin Wang, Amir Pakdel, Chunyi Zhi et al. - Recent progress in synthesis of twodimensional hexagonal boron nitride Haolin Wang, Yajuan Zhao, Yong Xie et al. - Recent advances in preparation, properties and device applications of twodimensional h-BN and its vertical heterostructures Huihui Yang, Feng Gao, Mingjin Dai et al

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