Borohydride-Assisted Surface Activation of Co3O4/CoFe2O4 Composite and Its Catalytic Activity for 4-Nitrophenol Reduction.

Abstract

Surface activation of catalysts is known to be an efficient process to enhance their activity in catalytic processes. The activation process includes the generation of oxygen vacancies, changing the nature of the catalyst surface from acidic to basic and vice versa, and the reduction of catalyst surface by H2. On the other hand, magnetically separable catalysts are highly beneficial for their utilization in water or biological fluid-based catalytic processes, as they can be easily guided to the target site and recovered. Here, we present the fabrication of CoFe2O4 and composites of Co3O4/CoFe2O4/α-Fe2O3 and Co/CoFe2O4/α-Fe2O3 through solution combustion process to utilize them as catalysts for 4-nitrophenol (4-NP) reduction. Although none of the as-prepared CoFe2O4 and Co3O4/CoFe2O4 was seen to be active in 4-NP reduction reaction, the surface of the composite gets activated by borohydride (NaBH4) treatment to act as a highly active catalyst for 4-NP reduction. X-ray photoelectron spectroscopy of the composite revealed the formation of metal-hydroxide (M–O–H) species of both Co and Fe at its surface due to borohydride treatment. The mechanism of the surface activation and the dynamics of 4-NP reduction of the surface-activated composite have been studied, proposing a possible pathway for the reduction of 4-NP.