Abstract
The neutral N-heterocyclic carbene stabilized boraalkene 1 conveniently prepared by a BH borenium/hydroboration route, forms stable copper, gold or palladium π-complexes. The polar boraalkene B=C system undergoes regioselective hydroboration reactions with the (C6F5)2BH or C6F5BH2•SMe2 boranes. The latter reaction involves a subsequent rearrangement that leads to internal hydride vs. isothiocyanate substituent exchange at the borane pair.
Full Text 
Sign-in/Register to access full text options
Sign-in/Register to access full text options 
Published version (
Free)
Free) 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a call
