Boosting zinc ion energy storage capability of inert MnO cathode by defect engineering

Abstract

Aqueous zinc ion battery constitutes a safe, stable and promising next-generation energy storage device, but suffers the lack of suitable host compounds for zinc ion storage. Development of a facile way to emerging cathode materials is strongly requested toward superior electrochemical activities and practical applications. Herein, defect engineering, i.e., simultaneous introduction of nitrogen dopant and oxygen vacancy into commercial and low-cost MnO, is proposed as a positive strategy to activate the originally inert phase for kinetically propelling its zinc ion storage capability. Both experimental characterization and theoretical calculations demonstrate that the nitrogen dopant significantly improves the electric conductivity of electrochemical inert MnO. Simultaneously, the oxygen vacancy creates sufficient large inserted channels and available activated adsorption sites for zinc ions storage. These synergistic structural advantages obviously ameliorate the electrochemical performance of inert MnO. Therefore, even without any conductive agent additive, the as-prepared material shows high specific capacity, superb rate capability, prolonged cycling stability and attractive energy density, which are dramatically superior to those of the pristine MnO as well as many other host cathode materials. This work presents fresh insights on the role of defect engineering in the enhancement of the intrinsic electrochemical reactivity of inert cathode, and an effective strategy for scalable fabrication of high-performance cathode for zinc ion battery.