Abstract
The external quantum efficiencies (EQEs) of the fluorescent organic light-emitting diodes (OLEDs) using exciplex as emitters are much lower than fluorescent OLEDs based on single-molecular thermally activated delayed fluorescent (TADF) emitters, even though exciplex can, in principle, realize 100% internal quantum efficiency (IQE). In addition, there are no clear guidelines to improve the efficiency in exciplex-based fluorescent OLEDs. Here, we quantitatively analyze the exciton dynamics influencing IQE of exciplex and demonstrate a fluorescent OLED with IQE of 100% and EQE of 25.2% at 150 K, which are improved from IQE of 48.3% and EQE of 11.0% at room temperature by reducing nonradiative transition of exciplex. This study shows that a high reverse intersystem crossing rate does not necessarily lead to efficient harvesting of triplet exciplex if it occurs with a high nonradiative transition rate (knr). We harvested more triplet exciplex by adopting exciplex with low knr and further suppressed the knr by freezing the exciplex to achieve IQE of 100%.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
