Boosting the Potassium-Ion Storage Performance in Soft Carbon Anodes by the Synergistic Effect of Optimized Molten Salt Medium and N/S Dual-Doping.

Abstract

Soft carbon is attracting tremendous attention as a promising anode material for potassium-ion batteries (PIBs) because of its graphitizable structure and adjustable interlayer distance. Herein, nitrogen/sulfur dual-doped porous soft carbon nanosheets (NSC) have been prepared with coal tar pitch as carbon precursors in an appropriate molten salt medium. The molten salt medium and N/S dual-doping are responsible for the formation of nanosheet-like morphology, abundant microporous channels with a high surface area of 436 m2 g-1, expanded interlamellar spacing of 0.378 nm, and enormous defect-induced active sites. These structural features are crucial for boosting potassium-ion storage performance, endowing the NSC to deliver a high potassiation storage capacity of 359 mAh g-1 at 100 mA g-1 and 115 mAh g-1 at 5.0 A g-1, and retaining 92.4% capacity retention at 1.0 A g-1 after 1000 cycles. More importantly, the pre-intercalation of K atom from the molten salts helps improve the initial Coulombic efficiency to 50%, which outperforms those of the recently reported carbon anode materials with large surface areas. The density functional theory calculations further illuminate that the N/S dual-doping can facilitate the adsorption of K-ion in carbon materials and decrease the ion diffusion energy barrier during the solid-state charge migration.